<?xml version="1.0" encoding="UTF-8" ?>

<PDBx:datablock datablockName="2OTQ-noatom"
   xmlns:PDBx="http://pdbml.pdb.org/schema/pdbx-v50.xsd"
   xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
   xsi:schemaLocation="http://pdbml.pdb.org/schema/pdbx-v50.xsd pdbx-v50.xsd">

   <PDBx:atom_sitesCategory>
      <PDBx:atom_sites entry_id="2OTQ">
         <PDBx:fract_transf_matrix11>1.000000</PDBx:fract_transf_matrix11>
         <PDBx:fract_transf_matrix12>0.000000</PDBx:fract_transf_matrix12>
         <PDBx:fract_transf_matrix13>0.000000</PDBx:fract_transf_matrix13>
         <PDBx:fract_transf_matrix21>0.000000</PDBx:fract_transf_matrix21>
         <PDBx:fract_transf_matrix22>1.000000</PDBx:fract_transf_matrix22>
         <PDBx:fract_transf_matrix23>0.000000</PDBx:fract_transf_matrix23>
         <PDBx:fract_transf_matrix31>0.000000</PDBx:fract_transf_matrix31>
         <PDBx:fract_transf_matrix32>0.000000</PDBx:fract_transf_matrix32>
         <PDBx:fract_transf_matrix33>1.000000</PDBx:fract_transf_matrix33>
         <PDBx:fract_transf_vector1>0.00000</PDBx:fract_transf_vector1>
         <PDBx:fract_transf_vector2>0.00000</PDBx:fract_transf_vector2>
         <PDBx:fract_transf_vector3>0.00000</PDBx:fract_transf_vector3>
      </PDBx:atom_sites>
   </PDBx:atom_sitesCategory>
   <PDBx:atom_typeCategory>
      <PDBx:atom_type symbol="C"></PDBx:atom_type>
      <PDBx:atom_type symbol="H"></PDBx:atom_type>
      <PDBx:atom_type symbol="N"></PDBx:atom_type>
      <PDBx:atom_type symbol="O"></PDBx:atom_type>
   </PDBx:atom_typeCategory>
   <PDBx:audit_authorCategory>
      <PDBx:audit_author pdbx_ordinal="1">
         <PDBx:name>Appelt, C.</PDBx:name>
      </PDBx:audit_author>
      <PDBx:audit_author pdbx_ordinal="2">
         <PDBx:name>Wesselowski, A.</PDBx:name>
      </PDBx:audit_author>
      <PDBx:audit_author pdbx_ordinal="3">
         <PDBx:name>Soderhall, J.A.</PDBx:name>
      </PDBx:audit_author>
      <PDBx:audit_author pdbx_ordinal="4">
         <PDBx:name>Dathe, M.</PDBx:name>
      </PDBx:audit_author>
      <PDBx:audit_author pdbx_ordinal="5">
         <PDBx:name>Schmieder, P.</PDBx:name>
      </PDBx:audit_author>
   </PDBx:audit_authorCategory>
   <PDBx:audit_conformCategory>
      <PDBx:audit_conform dict_name="mmcif_pdbx.dic" dict_version="5.397">
         <PDBx:dict_location>http://mmcif.pdb.org/dictionaries/ascii/mmcif_pdbx.dic</PDBx:dict_location>
      </PDBx:audit_conform>
   </PDBx:audit_conformCategory>
   <PDBx:cellCategory>
      <PDBx:cell entry_id="2OTQ">
         <PDBx:Z_PDB>1</PDBx:Z_PDB>
         <PDBx:angle_alpha>90.00</PDBx:angle_alpha>
         <PDBx:angle_beta>90.00</PDBx:angle_beta>
         <PDBx:angle_gamma>90.00</PDBx:angle_gamma>
         <PDBx:length_a>1.000</PDBx:length_a>
         <PDBx:length_b>1.000</PDBx:length_b>
         <PDBx:length_c>1.000</PDBx:length_c>
      </PDBx:cell>
   </PDBx:cellCategory>
   <PDBx:chem_compCategory>
      <PDBx:chem_comp id="ARG">
         <PDBx:formula>C6 H15 N4 O2 1</PDBx:formula>
         <PDBx:formula_weight>175.209</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>y</PDBx:mon_nstd_flag>
         <PDBx:name>ARGININE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="PHE">
         <PDBx:formula>C9 H11 N O2</PDBx:formula>
         <PDBx:formula_weight>165.189</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>y</PDBx:mon_nstd_flag>
         <PDBx:name>PHENYLALANINE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="TRP">
         <PDBx:formula>C11 H12 N2 O2</PDBx:formula>
         <PDBx:formula_weight>204.225</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>y</PDBx:mon_nstd_flag>
         <PDBx:name>TRYPTOPHAN</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
   </PDBx:chem_compCategory>
   <PDBx:chem_comp_atomCategory>
      <PDBx:chem_comp_atom atom_id="N" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>1</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>N</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CA" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>2</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>S</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="C" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>3</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="O" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>4</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>O</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CB" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>5</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CG" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>6</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CD" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>7</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="NE" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>8</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>N</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CZ" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>9</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="NH1" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>10</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>N</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="NH2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>11</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>N</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="OXT" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>12</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>O</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="H" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>13</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="H2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>14</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HA" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>15</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HB2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>16</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HB3" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>17</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HG2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>18</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HG3" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>19</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HD2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>20</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HD3" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>21</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HE" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>22</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HH11" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>23</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HH12" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>24</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HH21" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>25</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HH22" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>26</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HXT" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>27</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="N" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>28</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>N</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CA" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>29</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>S</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="C" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>30</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="O" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>31</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>O</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CB" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>32</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CG" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>33</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CD1" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>34</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CD2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>35</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CE1" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>36</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CE2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>37</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CZ" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>38</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="OXT" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>39</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>O</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="H" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>40</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="H2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>41</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HA" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>42</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HB2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>43</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HB3" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>44</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HD1" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>45</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HD2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>46</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HE1" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>47</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HE2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>48</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HZ" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>49</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HXT" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>50</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="N" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>51</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>N</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CA" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>52</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>S</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="C" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>53</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="O" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>54</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>O</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CB" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>55</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CG" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>56</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CD1" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>57</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CD2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>58</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="NE1" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>59</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>N</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CE2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>60</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CE3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>61</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CZ2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>62</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CZ3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>63</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="CH2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>64</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>C</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="OXT" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>65</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>O</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="H" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>66</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="H2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>67</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HA" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>68</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HB2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>69</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HB3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>70</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HD1" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>71</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HE1" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>72</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HE3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>73</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HZ2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>74</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HZ3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>75</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HH2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>76</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
      <PDBx:chem_comp_atom atom_id="HXT" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>77</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:type_symbol>H</PDBx:type_symbol>
      </PDBx:chem_comp_atom>
   </PDBx:chem_comp_atomCategory>
   <PDBx:chem_comp_bondCategory>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="CA" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>1</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="H" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>2</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="H2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>3</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="C" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>4</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="CB" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>5</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="HA" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>6</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="C" atom_id_2="O" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>7</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="C" atom_id_2="OXT" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>8</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="CG" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>9</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="HB2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>10</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="HB3" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>11</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CG" atom_id_2="CD" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>12</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CG" atom_id_2="HG2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>13</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CG" atom_id_2="HG3" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>14</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD" atom_id_2="NE" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>15</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD" atom_id_2="HD2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>16</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD" atom_id_2="HD3" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>17</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="NE" atom_id_2="CZ" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>18</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="NE" atom_id_2="HE" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>19</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CZ" atom_id_2="NH1" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>20</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CZ" atom_id_2="NH2" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>21</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="NH1" atom_id_2="HH11" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>22</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="NH1" atom_id_2="HH12" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>23</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="NH2" atom_id_2="HH21" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>24</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="NH2" atom_id_2="HH22" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>25</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="OXT" atom_id_2="HXT" comp_id="ARG">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>26</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="CA" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>27</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="H" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>28</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="H2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>29</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="C" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>30</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="CB" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>31</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="HA" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>32</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="C" atom_id_2="O" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>33</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="C" atom_id_2="OXT" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>34</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="CG" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>35</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="HB2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>36</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="HB3" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>37</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CG" atom_id_2="CD1" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>38</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CG" atom_id_2="CD2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>39</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD1" atom_id_2="CE1" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>40</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD1" atom_id_2="HD1" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>41</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD2" atom_id_2="CE2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>42</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD2" atom_id_2="HD2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>43</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CE1" atom_id_2="CZ" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>44</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CE1" atom_id_2="HE1" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>45</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CE2" atom_id_2="CZ" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>46</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CE2" atom_id_2="HE2" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>47</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CZ" atom_id_2="HZ" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>48</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="OXT" atom_id_2="HXT" comp_id="PHE">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>49</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="CA" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>50</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="H" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>51</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="N" atom_id_2="H2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>52</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="C" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>53</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="CB" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>54</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CA" atom_id_2="HA" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>55</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="C" atom_id_2="O" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>56</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="C" atom_id_2="OXT" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>57</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="CG" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>58</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="HB2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>59</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CB" atom_id_2="HB3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>60</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CG" atom_id_2="CD1" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>61</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CG" atom_id_2="CD2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>62</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD1" atom_id_2="NE1" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>63</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD1" atom_id_2="HD1" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>64</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD2" atom_id_2="CE2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>65</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CD2" atom_id_2="CE3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>66</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="NE1" atom_id_2="CE2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>67</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="NE1" atom_id_2="HE1" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>68</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CE2" atom_id_2="CZ2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>69</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CE3" atom_id_2="CZ3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>70</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CE3" atom_id_2="HE3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>71</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CZ2" atom_id_2="CH2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>72</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>doub</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CZ2" atom_id_2="HZ2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>73</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CZ3" atom_id_2="CH2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>Y</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>74</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CZ3" atom_id_2="HZ3" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>75</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="CH2" atom_id_2="HH2" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>76</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
      <PDBx:chem_comp_bond atom_id_1="OXT" atom_id_2="HXT" comp_id="TRP">
         <PDBx:pdbx_aromatic_flag>N</PDBx:pdbx_aromatic_flag>
         <PDBx:pdbx_ordinal>77</PDBx:pdbx_ordinal>
         <PDBx:pdbx_stereo_config>N</PDBx:pdbx_stereo_config>
         <PDBx:value_order>sing</PDBx:value_order>
      </PDBx:chem_comp_bond>
   </PDBx:chem_comp_bondCategory>
   <PDBx:citationCategory>
      <PDBx:citation id="primary">
         <PDBx:country>UK</PDBx:country>
         <PDBx:journal_abbrev>J.Pept.Sci.</PDBx:journal_abbrev>
         <PDBx:journal_id_ASTM>JPSIEI</PDBx:journal_id_ASTM>
         <PDBx:journal_id_CSD>1225</PDBx:journal_id_CSD>
         <PDBx:journal_id_ISSN>1075-2617</PDBx:journal_id_ISSN>
         <PDBx:journal_volume>14</PDBx:journal_volume>
         <PDBx:page_first>524</PDBx:page_first>
         <PDBx:page_last>527</PDBx:page_last>
         <PDBx:pdbx_database_id_DOI>10.1002/psc.924</PDBx:pdbx_database_id_DOI>
         <PDBx:pdbx_database_id_PubMed>17985394</PDBx:pdbx_database_id_PubMed>
         <PDBx:title>Structures of cyclic, antimicrobial peptides in a membrane-mimicking environment define requirements for activity.</PDBx:title>
         <PDBx:year>2007</PDBx:year>
      </PDBx:citation>
   </PDBx:citationCategory>
   <PDBx:citation_authorCategory>
      <PDBx:citation_author citation_id="primary" name="Appelt, C." ordinal="1">
      </PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Wessolowski, A." ordinal="2">
      </PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Dathe, M." ordinal="3">
      </PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Schmieder, P." ordinal="4">
      </PDBx:citation_author>
   </PDBx:citation_authorCategory>
   <PDBx:database_2Category>
      <PDBx:database_2 database_code="2OTQ" database_id="PDB">
         <PDBx:pdbx_DOI>10.2210/pdb2otq/pdb</PDBx:pdbx_DOI>
         <PDBx:pdbx_database_accession>pdb_00002otq</PDBx:pdbx_database_accession>
      </PDBx:database_2>
      <PDBx:database_2 database_code="RCSB041573" database_id="RCSB">
      </PDBx:database_2>
      <PDBx:database_2 database_code="D_1000041573" database_id="WWPDB">
      </PDBx:database_2>
   </PDBx:database_2Category>
   <PDBx:diffrnCategory>
      <PDBx:diffrn id="1">
         <PDBx:crystal_id>1</PDBx:crystal_id>
      </PDBx:diffrn>
   </PDBx:diffrnCategory>
   <PDBx:diffrn_radiationCategory>
      <PDBx:diffrn_radiation diffrn_id="1">
         <PDBx:pdbx_diffrn_protocol>SINGLE WAVELENGTH</PDBx:pdbx_diffrn_protocol>
         <PDBx:pdbx_monochromatic_or_laue_m_l>M</PDBx:pdbx_monochromatic_or_laue_m_l>
         <PDBx:wavelength_id>1</PDBx:wavelength_id>
      </PDBx:diffrn_radiation>
   </PDBx:diffrn_radiationCategory>
   <PDBx:diffrn_radiation_wavelengthCategory>
      <PDBx:diffrn_radiation_wavelength id="1">
         <PDBx:wavelength xsi:nil="true" />
         <PDBx:wt>1.0</PDBx:wt>
      </PDBx:diffrn_radiation_wavelength>
   </PDBx:diffrn_radiation_wavelengthCategory>
   <PDBx:entityCategory>
      <PDBx:entity id="1">
         <PDBx:formula_weight>1009.190</PDBx:formula_weight>
         <PDBx:pdbx_description>cRW3 cationic antimicrobial peptide</PDBx:pdbx_description>
         <PDBx:pdbx_number_of_molecules>1</PDBx:pdbx_number_of_molecules>
         <PDBx:src_method>syn</PDBx:src_method>
         <PDBx:type>polymer</PDBx:type>
      </PDBx:entity>
   </PDBx:entityCategory>
   <PDBx:entity_polyCategory>
      <PDBx:entity_poly entity_id="1">
         <PDBx:nstd_linkage>no</PDBx:nstd_linkage>
         <PDBx:nstd_monomer>no</PDBx:nstd_monomer>
         <PDBx:pdbx_seq_one_letter_code>RRWFWR</PDBx:pdbx_seq_one_letter_code>
         <PDBx:pdbx_seq_one_letter_code_can>RRWFWR</PDBx:pdbx_seq_one_letter_code_can>
         <PDBx:pdbx_strand_id>A</PDBx:pdbx_strand_id>
         <PDBx:type>polypeptide(L)</PDBx:type>
      </PDBx:entity_poly>
   </PDBx:entity_polyCategory>
   <PDBx:entity_poly_seqCategory>
      <PDBx:entity_poly_seq entity_id="1" mon_id="ARG" num="1">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="ARG" num="2">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="TRP" num="3">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="PHE" num="4">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="TRP" num="5">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="ARG" num="6">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
   </PDBx:entity_poly_seqCategory>
   <PDBx:entryCategory>
      <PDBx:entry id="2OTQ"></PDBx:entry>
   </PDBx:entryCategory>
   <PDBx:exptlCategory>
      <PDBx:exptl entry_id="2OTQ" method="SOLUTION NMR">
      </PDBx:exptl>
   </PDBx:exptlCategory>
   <PDBx:exptl_crystalCategory>
      <PDBx:exptl_crystal id="1">
      </PDBx:exptl_crystal>
   </PDBx:exptl_crystalCategory>
   <PDBx:pdbx_audit_revision_categoryCategory>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="1" revision_ordinal="3">
         <PDBx:category>database_2</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="2" revision_ordinal="3">
         <PDBx:category>pdbx_nmr_software</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="3" revision_ordinal="3">
         <PDBx:category>pdbx_struct_assembly</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="4" revision_ordinal="3">
         <PDBx:category>pdbx_struct_oper_list</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="5" revision_ordinal="3">
         <PDBx:category>struct_conn</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="6" revision_ordinal="4">
         <PDBx:category>chem_comp_atom</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="7" revision_ordinal="4">
         <PDBx:category>chem_comp_bond</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="8" revision_ordinal="4">
         <PDBx:category>pdbx_entry_details</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
      <PDBx:pdbx_audit_revision_category data_content_type="Structure model" ordinal="9" revision_ordinal="4">
         <PDBx:category>pdbx_modification_feature</PDBx:category>
      </PDBx:pdbx_audit_revision_category>
   </PDBx:pdbx_audit_revision_categoryCategory>
   <PDBx:pdbx_audit_revision_detailsCategory>
      <PDBx:pdbx_audit_revision_details data_content_type="Structure model" ordinal="1" revision_ordinal="1">
         <PDBx:provider>repository</PDBx:provider>
         <PDBx:type>Initial release</PDBx:type>
      </PDBx:pdbx_audit_revision_details>
   </PDBx:pdbx_audit_revision_detailsCategory>
   <PDBx:pdbx_audit_revision_groupCategory>
      <PDBx:pdbx_audit_revision_group data_content_type="Structure model" ordinal="1" revision_ordinal="2">
         <PDBx:group>Version format compliance</PDBx:group>
      </PDBx:pdbx_audit_revision_group>
      <PDBx:pdbx_audit_revision_group data_content_type="Structure model" ordinal="2" revision_ordinal="3">
         <PDBx:group>Data collection</PDBx:group>
      </PDBx:pdbx_audit_revision_group>
      <PDBx:pdbx_audit_revision_group data_content_type="Structure model" ordinal="3" revision_ordinal="3">
         <PDBx:group>Database references</PDBx:group>
      </PDBx:pdbx_audit_revision_group>
      <PDBx:pdbx_audit_revision_group data_content_type="Structure model" ordinal="4" revision_ordinal="3">
         <PDBx:group>Derived calculations</PDBx:group>
      </PDBx:pdbx_audit_revision_group>
      <PDBx:pdbx_audit_revision_group data_content_type="Structure model" ordinal="5" revision_ordinal="4">
         <PDBx:group>Data collection</PDBx:group>
      </PDBx:pdbx_audit_revision_group>
      <PDBx:pdbx_audit_revision_group data_content_type="Structure model" ordinal="6" revision_ordinal="4">
         <PDBx:group>Structure summary</PDBx:group>
      </PDBx:pdbx_audit_revision_group>
   </PDBx:pdbx_audit_revision_groupCategory>
   <PDBx:pdbx_audit_revision_historyCategory>
      <PDBx:pdbx_audit_revision_history data_content_type="Structure model" ordinal="1">
         <PDBx:major_revision>1</PDBx:major_revision>
         <PDBx:minor_revision>0</PDBx:minor_revision>
         <PDBx:revision_date>2007-12-25</PDBx:revision_date>
      </PDBx:pdbx_audit_revision_history>
      <PDBx:pdbx_audit_revision_history data_content_type="Structure model" ordinal="2">
         <PDBx:major_revision>1</PDBx:major_revision>
         <PDBx:minor_revision>1</PDBx:minor_revision>
         <PDBx:revision_date>2011-07-13</PDBx:revision_date>
      </PDBx:pdbx_audit_revision_history>
      <PDBx:pdbx_audit_revision_history data_content_type="Structure model" ordinal="3">
         <PDBx:major_revision>1</PDBx:major_revision>
         <PDBx:minor_revision>2</PDBx:minor_revision>
         <PDBx:revision_date>2022-03-16</PDBx:revision_date>
      </PDBx:pdbx_audit_revision_history>
      <PDBx:pdbx_audit_revision_history data_content_type="Structure model" ordinal="4">
         <PDBx:major_revision>1</PDBx:major_revision>
         <PDBx:minor_revision>3</PDBx:minor_revision>
         <PDBx:revision_date>2024-10-09</PDBx:revision_date>
      </PDBx:pdbx_audit_revision_history>
   </PDBx:pdbx_audit_revision_historyCategory>
   <PDBx:pdbx_audit_revision_itemCategory>
      <PDBx:pdbx_audit_revision_item data_content_type="Structure model" ordinal="1" revision_ordinal="3">
         <PDBx:item>_database_2.pdbx_DOI</PDBx:item>
      </PDBx:pdbx_audit_revision_item>
      <PDBx:pdbx_audit_revision_item data_content_type="Structure model" ordinal="2" revision_ordinal="3">
         <PDBx:item>_database_2.pdbx_database_accession</PDBx:item>
      </PDBx:pdbx_audit_revision_item>
      <PDBx:pdbx_audit_revision_item data_content_type="Structure model" ordinal="3" revision_ordinal="3">
         <PDBx:item>_pdbx_nmr_software.name</PDBx:item>
      </PDBx:pdbx_audit_revision_item>
      <PDBx:pdbx_audit_revision_item data_content_type="Structure model" ordinal="4" revision_ordinal="3">
         <PDBx:item>_struct_conn.pdbx_leaving_atom_flag</PDBx:item>
      </PDBx:pdbx_audit_revision_item>
   </PDBx:pdbx_audit_revision_itemCategory>
   <PDBx:pdbx_database_relatedCategory>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="1QVK" db_name="PDB">
         <PDBx:details>Related peptide</PDBx:details>
      </PDBx:pdbx_database_related>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="1QVL" db_name="PDB">
         <PDBx:details>Related peptide</PDBx:details>
      </PDBx:pdbx_database_related>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="1SKI" db_name="PDB">
         <PDBx:details>Related peptide</PDBx:details>
      </PDBx:pdbx_database_related>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="1SKK" db_name="PDB">
         <PDBx:details>Related peptide</PDBx:details>
      </PDBx:pdbx_database_related>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="1SKL" db_name="PDB">
         <PDBx:details>Related peptide</PDBx:details>
      </PDBx:pdbx_database_related>
   </PDBx:pdbx_database_relatedCategory>
   <PDBx:pdbx_database_statusCategory>
      <PDBx:pdbx_database_status entry_id="2OTQ">
         <PDBx:deposit_site>RCSB</PDBx:deposit_site>
         <PDBx:pdb_format_compatible>Y</PDBx:pdb_format_compatible>
         <PDBx:process_site>RCSB</PDBx:process_site>
         <PDBx:recvd_initial_deposition_date>2007-02-09</PDBx:recvd_initial_deposition_date>
         <PDBx:status_code>REL</PDBx:status_code>
         <PDBx:status_code_mr>REL</PDBx:status_code_mr>
      </PDBx:pdbx_database_status>
   </PDBx:pdbx_database_statusCategory>
   <PDBx:pdbx_entry_detailsCategory>
      <PDBx:pdbx_entry_details entry_id="2OTQ">
         <PDBx:has_protein_modification>Y</PDBx:has_protein_modification>
      </PDBx:pdbx_entry_details>
   </PDBx:pdbx_entry_detailsCategory>
   <PDBx:pdbx_modification_featureCategory>
      <PDBx:pdbx_modification_feature ordinal="1">
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>1</PDBx:auth_seq_id>
         <PDBx:category>Non-standard linkage</PDBx:category>
         <PDBx:comp_id_linking_atom>N</PDBx:comp_id_linking_atom>
         <PDBx:label_asym_id>A</PDBx:label_asym_id>
         <PDBx:label_comp_id>ARG</PDBx:label_comp_id>
         <PDBx:label_seq_id>1</PDBx:label_seq_id>
         <PDBx:modified_residue_auth_asym_id>A</PDBx:modified_residue_auth_asym_id>
         <PDBx:modified_residue_auth_comp_id>ARG</PDBx:modified_residue_auth_comp_id>
         <PDBx:modified_residue_auth_seq_id>6</PDBx:modified_residue_auth_seq_id>
         <PDBx:modified_residue_id xsi:nil="true" />
         <PDBx:modified_residue_id_linking_atom>C</PDBx:modified_residue_id_linking_atom>
         <PDBx:modified_residue_label_asym_id>A</PDBx:modified_residue_label_asym_id>
         <PDBx:modified_residue_label_comp_id>ARG</PDBx:modified_residue_label_comp_id>
         <PDBx:modified_residue_label_seq_id>6</PDBx:modified_residue_label_seq_id>
         <PDBx:modified_residue_symmetry>1_555</PDBx:modified_residue_symmetry>
         <PDBx:ref_comp_id xsi:nil="true" />
         <PDBx:ref_pcm_id xsi:nil="true" />
         <PDBx:symmetry>1_555</PDBx:symmetry>
         <PDBx:type>None</PDBx:type>
      </PDBx:pdbx_modification_feature>
   </PDBx:pdbx_modification_featureCategory>
   <PDBx:pdbx_nmr_detailsCategory>
      <PDBx:pdbx_nmr_details entry_id="2OTQ">
         <PDBx:text>This structure was determined using standard 2D homonuclear techniques.</PDBx:text>
      </PDBx:pdbx_nmr_details>
   </PDBx:pdbx_nmr_detailsCategory>
   <PDBx:pdbx_nmr_ensembleCategory>
      <PDBx:pdbx_nmr_ensemble entry_id="2OTQ">
         <PDBx:conformer_selection_criteria>structures with the lowest energy</PDBx:conformer_selection_criteria>
         <PDBx:conformers_calculated_total_number>100</PDBx:conformers_calculated_total_number>
         <PDBx:conformers_submitted_total_number>10</PDBx:conformers_submitted_total_number>
      </PDBx:pdbx_nmr_ensemble>
   </PDBx:pdbx_nmr_ensembleCategory>
   <PDBx:pdbx_nmr_exptlCategory>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="1" solution_id="1">
         <PDBx:type>2D NOESY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="2" solution_id="1">
         <PDBx:type>2D TOCSY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="3" solution_id="1">
         <PDBx:type>DQF-COSY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
   </PDBx:pdbx_nmr_exptlCategory>
   <PDBx:pdbx_nmr_exptl_sample_conditionsCategory>
      <PDBx:pdbx_nmr_exptl_sample_conditions conditions_id="1">
         <PDBx:pH>6.3</PDBx:pH>
         <PDBx:pressure>1</PDBx:pressure>
         <PDBx:pressure_units>atm</PDBx:pressure_units>
         <PDBx:temperature>300</PDBx:temperature>
         <PDBx:temperature_units>K</PDBx:temperature_units>
      </PDBx:pdbx_nmr_exptl_sample_conditions>
   </PDBx:pdbx_nmr_exptl_sample_conditionsCategory>
   <PDBx:pdbx_nmr_refineCategory>
      <PDBx:pdbx_nmr_refine entry_id="2OTQ" software_ordinal="1">
         <PDBx:method>simulated annealing</PDBx:method>
      </PDBx:pdbx_nmr_refine>
   </PDBx:pdbx_nmr_refineCategory>
   <PDBx:pdbx_nmr_representativeCategory>
      <PDBx:pdbx_nmr_representative entry_id="2OTQ">
         <PDBx:conformer_id>1</PDBx:conformer_id>
         <PDBx:selection_criteria>lowest energy</PDBx:selection_criteria>
      </PDBx:pdbx_nmr_representative>
   </PDBx:pdbx_nmr_representativeCategory>
   <PDBx:pdbx_nmr_sample_detailsCategory>
      <PDBx:pdbx_nmr_sample_details solution_id="1">
         <PDBx:contents>50mM DPC-d38, H2O:D2O 9:1</PDBx:contents>
         <PDBx:solvent_system>H2O:D2O 9:1</PDBx:solvent_system>
      </PDBx:pdbx_nmr_sample_details>
   </PDBx:pdbx_nmr_sample_detailsCategory>
   <PDBx:pdbx_nmr_softwareCategory>
      <PDBx:pdbx_nmr_software ordinal="1">
         <PDBx:authors>Bruker</PDBx:authors>
         <PDBx:classification>collection</PDBx:classification>
         <PDBx:name>XwinNMR</PDBx:name>
         <PDBx:version>2.6</PDBx:version>
      </PDBx:pdbx_nmr_software>
      <PDBx:pdbx_nmr_software ordinal="2">
         <PDBx:authors>Goddard, T.D., Kneller, D.G.</PDBx:authors>
         <PDBx:classification>data analysis</PDBx:classification>
         <PDBx:name>Sparky</PDBx:name>
         <PDBx:version>3.1</PDBx:version>
      </PDBx:pdbx_nmr_software>
      <PDBx:pdbx_nmr_software ordinal="3">
         <PDBx:authors>Case, D.A.</PDBx:authors>
         <PDBx:classification>structure solution</PDBx:classification>
         <PDBx:name>Amber</PDBx:name>
         <PDBx:version>6.0</PDBx:version>
      </PDBx:pdbx_nmr_software>
      <PDBx:pdbx_nmr_software ordinal="4">
         <PDBx:authors>Case, D.A.</PDBx:authors>
         <PDBx:classification>refinement</PDBx:classification>
         <PDBx:name>Amber</PDBx:name>
         <PDBx:version>6.0</PDBx:version>
      </PDBx:pdbx_nmr_software>
   </PDBx:pdbx_nmr_softwareCategory>
   <PDBx:pdbx_nmr_spectrometerCategory>
      <PDBx:pdbx_nmr_spectrometer spectrometer_id="1">
         <PDBx:field_strength>600</PDBx:field_strength>
         <PDBx:manufacturer>Bruker</PDBx:manufacturer>
         <PDBx:model>DRX</PDBx:model>
      </PDBx:pdbx_nmr_spectrometer>
   </PDBx:pdbx_nmr_spectrometerCategory>
   <PDBx:pdbx_poly_seq_schemeCategory>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="ARG" seq_id="1">
         <PDBx:auth_mon_id>ARG</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>1</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>1</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>ARG</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>1</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="ARG" seq_id="2">
         <PDBx:auth_mon_id>ARG</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>2</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>2</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>ARG</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>2</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="TRP" seq_id="3">
         <PDBx:auth_mon_id>TRP</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>3</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>3</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>TRP</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>3</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="PHE" seq_id="4">
         <PDBx:auth_mon_id>PHE</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>4</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>4</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>PHE</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>4</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="TRP" seq_id="5">
         <PDBx:auth_mon_id>TRP</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>5</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>5</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>TRP</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>5</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="ARG" seq_id="6">
         <PDBx:auth_mon_id>ARG</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>6</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>6</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>ARG</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>6</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
   </PDBx:pdbx_poly_seq_schemeCategory>
   <PDBx:pdbx_struct_assemblyCategory>
      <PDBx:pdbx_struct_assembly id="1">
         <PDBx:details>author_defined_assembly</PDBx:details>
         <PDBx:oligomeric_count>1</PDBx:oligomeric_count>
         <PDBx:oligomeric_details>monomeric</PDBx:oligomeric_details>
      </PDBx:pdbx_struct_assembly>
   </PDBx:pdbx_struct_assemblyCategory>
   <PDBx:pdbx_struct_assembly_genCategory>
      <PDBx:pdbx_struct_assembly_gen assembly_id="1" asym_id_list="A" oper_expression="1"></PDBx:pdbx_struct_assembly_gen>
   </PDBx:pdbx_struct_assembly_genCategory>
   <PDBx:pdbx_struct_oper_listCategory>
      <PDBx:pdbx_struct_oper_list id="1">
         <PDBx:matrix11>1.0000000000</PDBx:matrix11>
         <PDBx:matrix12>0.0000000000</PDBx:matrix12>
         <PDBx:matrix13>0.0000000000</PDBx:matrix13>
         <PDBx:matrix21>0.0000000000</PDBx:matrix21>
         <PDBx:matrix22>1.0000000000</PDBx:matrix22>
         <PDBx:matrix23>0.0000000000</PDBx:matrix23>
         <PDBx:matrix31>0.0000000000</PDBx:matrix31>
         <PDBx:matrix32>0.0000000000</PDBx:matrix32>
         <PDBx:matrix33>1.0000000000</PDBx:matrix33>
         <PDBx:name>1_555</PDBx:name>
         <PDBx:symmetry_operation>x,y,z</PDBx:symmetry_operation>
         <PDBx:type>identity operation</PDBx:type>
         <PDBx:vector1>0.0000000000</PDBx:vector1>
         <PDBx:vector2>0.0000000000</PDBx:vector2>
         <PDBx:vector3>0.0000000000</PDBx:vector3>
      </PDBx:pdbx_struct_oper_list>
   </PDBx:pdbx_struct_oper_listCategory>
   <PDBx:pdbx_validate_torsionCategory>
      <PDBx:pdbx_validate_torsion id="1">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>-25.99</PDBx:phi>
         <PDBx:psi>-52.37</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="2">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-149.12</PDBx:phi>
         <PDBx:psi>10.19</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="3">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>76.35</PDBx:phi>
         <PDBx:psi>-68.01</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="4">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-164.73</PDBx:phi>
         <PDBx:psi>2.85</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="5">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>PHE</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-121.07</PDBx:phi>
         <PDBx:psi>-162.53</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="6">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>56.38</PDBx:phi>
         <PDBx:psi>-76.41</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="7">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-151.55</PDBx:phi>
         <PDBx:psi>5.12</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="8">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>PHE</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-119.36</PDBx:phi>
         <PDBx:psi>-159.56</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="9">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>79.75</PDBx:phi>
         <PDBx:psi>-64.72</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="10">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-163.08</PDBx:phi>
         <PDBx:psi>6.91</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="11">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>75.06</PDBx:phi>
         <PDBx:psi>-59.97</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="12">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-164.61</PDBx:phi>
         <PDBx:psi>8.62</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="13">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>59.35</PDBx:phi>
         <PDBx:psi>-82.67</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="14">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-151.52</PDBx:phi>
         <PDBx:psi>-23.95</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="15">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>61.11</PDBx:phi>
         <PDBx:psi>-61.84</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="16">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>59.24</PDBx:phi>
         <PDBx:psi>-80.45</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="17">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>52.12</PDBx:phi>
         <PDBx:psi>-146.13</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="18">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>ARG</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>79.61</PDBx:phi>
         <PDBx:psi>-66.57</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="19">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-165.18</PDBx:phi>
         <PDBx:psi>-20.42</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
   </PDBx:pdbx_validate_torsionCategory>
   <PDBx:structCategory>
      <PDBx:struct entry_id="2OTQ">
         <PDBx:title>Structure of the antimicrobial peptide cyclo(RRWFWR) bound to DPC micelles</PDBx:title>
      </PDBx:struct>
   </PDBx:structCategory>
   <PDBx:struct_asymCategory>
      <PDBx:struct_asym id="A">
         <PDBx:entity_id>1</PDBx:entity_id>
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
      </PDBx:struct_asym>
   </PDBx:struct_asymCategory>
   <PDBx:struct_biolCategory>
      <PDBx:struct_biol id="1">
      </PDBx:struct_biol>
   </PDBx:struct_biolCategory>
   <PDBx:struct_connCategory>
      <PDBx:struct_conn id="covale1">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.341</PDBx:pdbx_dist_value>
         <PDBx:pdbx_leaving_atom_flag>both</PDBx:pdbx_leaving_atom_flag>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>ARG</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>1</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>N</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>ARG</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>1</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>ARG</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>6</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>C</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>ARG</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>6</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
   </PDBx:struct_connCategory>
   <PDBx:struct_conn_typeCategory>
      <PDBx:struct_conn_type id="covale">
      </PDBx:struct_conn_type>
   </PDBx:struct_conn_typeCategory>
   <PDBx:struct_keywordsCategory>
      <PDBx:struct_keywords entry_id="2OTQ">
         <PDBx:pdbx_keywords>ANTIMICROBIAL PROTEIN</PDBx:pdbx_keywords>
         <PDBx:text>cationic antimicrobial peptide, ANTIMICROBIAL PROTEIN</PDBx:text>
      </PDBx:struct_keywords>
   </PDBx:struct_keywordsCategory>
   <PDBx:struct_refCategory>
      <PDBx:struct_ref id="1">
         <PDBx:db_code>2OTQ</PDBx:db_code>
         <PDBx:db_name>PDB</PDBx:db_name>
         <PDBx:entity_id>1</PDBx:entity_id>
         <PDBx:pdbx_db_accession>2OTQ</PDBx:pdbx_db_accession>
      </PDBx:struct_ref>
   </PDBx:struct_refCategory>
   <PDBx:struct_ref_seqCategory>
      <PDBx:struct_ref_seq align_id="1">
         <PDBx:db_align_beg>1</PDBx:db_align_beg>
         <PDBx:db_align_end>6</PDBx:db_align_end>
         <PDBx:pdbx_PDB_id_code>2OTQ</PDBx:pdbx_PDB_id_code>
         <PDBx:pdbx_auth_seq_align_beg>1</PDBx:pdbx_auth_seq_align_beg>
         <PDBx:pdbx_auth_seq_align_end>6</PDBx:pdbx_auth_seq_align_end>
         <PDBx:pdbx_db_accession>2OTQ</PDBx:pdbx_db_accession>
         <PDBx:pdbx_strand_id>A</PDBx:pdbx_strand_id>
         <PDBx:ref_id>1</PDBx:ref_id>
         <PDBx:seq_align_beg>1</PDBx:seq_align_beg>
         <PDBx:seq_align_end>6</PDBx:seq_align_end>
      </PDBx:struct_ref_seq>
   </PDBx:struct_ref_seqCategory>
   <PDBx:symmetryCategory>
      <PDBx:symmetry entry_id="2OTQ">
         <PDBx:Int_Tables_number>1</PDBx:Int_Tables_number>
         <PDBx:space_group_name_H-M>P 1</PDBx:space_group_name_H-M>
      </PDBx:symmetry>
   </PDBx:symmetryCategory>
</PDBx:datablock>
